Knowledge in Physical Chemistry

Energy and Power

Work,Power,Energy,Mechanical Energy,Collisions,

Chemistry for KIIT University

Study Material on Chemistry for B.Tech

Column Chromatography

A basic concept in Analytical Chemistry, to separate mixture organic sample mainly in liquid form.

Atomic Absorption Spectrometry- A useful tool in scientific research

Every year, we are listening to the news of ever increasing pollution levels. It creates havoc in different ways, somewhere it is form of smog(Delhi) while in other places it is in form of soil erosion, loud noise, etc. We also get continuous reports of how Pollution Control Department is trying to curb these pollution levels by imposing fines on industries, coming up with new bills to be passed in legislation, etc. On a scientific level,there, lies a method to treat the issues of contamination. This is Atomic Absorption Spectrometry which is quite a important method nowadays as researchers use it to detect heavy metals in water, soil and air. AAS Method is basically a technique used for the determination of single elements in the chemical compounds using the absorption of optical radiation(light) by free atoms in the gaseous state. The principle of the technique involves using atomic absorption spectrum of a sample in order to assess the concentration of specific analyte in it. And moreover, to establish the relation between measured absorbance value and the analyte concentration, it relies on Beer Lambert’s Law. AAS detects elements from samples through application of characteristic wavelengths of electromagnetic radiation from a light source. So, basically what happens in this technique? First of all, a sample to be analyzed is taken and converted to liquid (most commonly used) or gaseous form. The solution is drawn in through a small tube present in the front of the device and taken to nebulizer where the solution is broken up into a fine mist(similar to an aerosol spray). The fine mist is carried to the atomizer, such as flame, by a carrier gas. When the sample reaches the flame, the intense heat evaporates the sample and leaves a fine dry residue which are the atoms in the ground state. These ground state atoms are excited with the electromagnetic radiation of specific wavelength. Once excited, they absorb the radiation given to them. The amount of absorbance value is measured and it indicates the absorbance for a particular element. The electromagnetic radiation comes from a hollow cathode lamp which has argon or neon gas inside. And the flame is typically Acetylene gas or Nitrous oxide gas. Atomization using flame are also called as FAAS (Flame Atomic Absorption Spectrometry) The AAS method is extremely used in detection of heavy metals, for analyzing soil and plants for mineral necessary for growth. It is also applied , in forensic for substance identification, in food industry, for quality assurance and testing for contamination, in pharmaceutical, for detecting impurities in drugs. So, this method is quite useful and will be in the near future. When our environment has become hazardous, methods like AAS become important all the more. It is also necessary to come up with new scientific methods to combat the harm on our nature.

1st Semester,Chemistry,KIIT University

Specially for kiit students.

ENGINEERING CHEMISTRY

Engineering Chemistry The article gives the ppt's about all the major topics in the engineering chemistry. it is needed for every engineering graduate in his UG course.Moreover the information in these ppt present the entire core knowledge of the subject to the students. The contents in the article 1.Atomic structures 2.Polymers 3.Water technology 4. Electro Chemistry 5. Corrosion 6. Organic Chemistry The content in the ppt are self explanatory and prepared by experienced faculty for the easy understanding of the students and the contained information in the ppt is taken from the reputed books and recognized authors. The files are prepared in a student friendly manner for the better understanding of the subject by the student.

Interhalogens

An interhalogen compound is a molecule which contains two or more different halogen atoms (fluorine, chlorine, bromine, iodine, or astatine) and no atoms of elements from any other group. This document explains the interhalogen compounds with suitable examples using VSEPR theory

CHEMICAL KINETICS ( CLASS 12TH)

Chemical kinetics is the branch of chemistry that deals with the study of reaction rates and thier mechanisms. This file includes rate of reaction,factors affecting rate of reaction,order of reaction,probability factor

Halogen compounds

Organic halogen compounds are a large class of natural and synthetic chemicals that contain one or more halogens (fluorine, chlorine, bromine, or iodine) combined with carbon and other elements. The simplest organochlorine compound is chloromethane, also called methyl chloride(CH3Cl) This file includes types of nucleophilic substitution reaction and their mechanisms

S-Block Elements

S-Block Notes 1st Group, Alkali Metals,Physical Properties,Chemical Properties,Anomalous Behaviour of Lithium, Diagonal relationship of Li & Mg, Some Important compounds of Alkali Metals, NaOH preparation,Properties,Microcosmic Salts,Alkaline Earth Metals,Physical properties,Chemical Properties,Carbonates & Bicarbonates,Sulphates,Carbides,Solution in Ammonia,Anomalous Behaviour of Berillium,Diagonal relationship of Be & Al,, Some Important compounds of Alkali Earth Metals

Hydrogen & Its Compounds

Hydrogen Bonding Isotopes,Preparation,Hydrides & Hydrides Gap,Hardness Of Water, Hydrogen Peroxide(physical & Chemical Properties)

Chemical Bonding

Chemical Bonding Lewis Concept,Lattice Energy,Polarisation,covalent Bond(Lewis Theory,VSEPR Theory,VBT),Hybridization ,Properties Of Covalent Bond, Dragos Rule,Bent Rule, Intermolecular forces in covalent compounds,Hydrogen Bonding